Electrochemistry
13 free MDCAT Chemistry MCQs on Electrochemistry (PM&DC syllabus), each with the answer, an explanation and the textbook line it comes from. Tap to check, no sign-up.
Tap an answer to check it · 13 questions
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Question 1
The mass of a substance liberated at an electrode when one coulomb of electricity is passed is its:Show answer and explanation
Answer: C) Electrochemical equivalent
Z in W = ZQ (Faraday's first law). Source: Chemistry 11 KPK (taleem360.com), p. 382.
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Question 2
The oxidation number of Cr in K2Cr2O7 is:Show answer and explanation
Answer: C) +6
2(+1) + 2x + 7(-2) = 0, so 2x = 12 and x = +6. Source: Chemistry 11 KPK (taleem360.com), p. 365.
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Question 3
A cell in which a non-spontaneous redox reaction is carried out by passing an electric current is a/an:Show answer and explanation
Answer: A) Electrolytic cell
Galvanic (voltaic) cells such as the Daniell cell run spontaneous reactions. Source: Chemistry 11 KPK (taleem360.com), p. 378.
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Question 4
Zinc is the anode in a Daniell cell but the cathode when coupled with aluminium, because the reduction potential of zinc is:Show answer and explanation
Answer: B) Higher than aluminium
Zn (-0.76 V) is above Cu (+0.34 V) but below Al (-1.67 V); the higher reduction potential is the cathode. Source: Chemistry 11 KPK (taleem360.com), p. 378.
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Question 5
In terms of oxidation number, oxidation is:Show answer and explanation
Answer: C) An increase in oxidation number
Loss of electrons raises the oxidation number. Source: Chemistry 11 KPK (taleem360.com), p. 364.
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Question 6
An oxidizing agent:Show answer and explanation
Answer: D) Gets reduced itself
It gains electrons and its oxidation number decreases (e.g. Cl2 0 -> -1). Source: Chemistry 11 KPK (taleem360.com), p. 366.
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Question 7
The oxidation number of an element in its free state is:Show answer and explanation
Answer: A) Zero
e.g. H2, O2, Na metal. Source: Chemistry 11 KPK (taleem360.com), p. 364.
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Question 8
In an electrochemical cell, oxidation takes place at the:Show answer and explanation
Answer: B) Anode
Reduction takes place at the cathode. Source: Chemistry 11 KPK (taleem360.com), p. 391.
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Question 9
Zinc displaces copper from CuSO4 solution because zinc has a:Show answer and explanation
Answer: C) Lower reduction potential
Zn (-0.76 V) lies above Cu (+0.34 V) in the series and gives electrons to Cu2+. Source: Chemistry 11 KPK (taleem360.com), p. 378.
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Question 10
In Nelson's cell for the electrolysis of brine, the NaOH formed is collected at the:Show answer and explanation
Answer: D) Bottom of the cell
Cl2 is released at the graphite anode and H2 at the perforated steel cathode. Source: Chemistry 11 KPK (taleem360.com), p. 380.
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Question 11
Chemically, the rust on iron is:Show answer and explanation
Answer: C) Hydrated iron(III) oxide
Fe2O3.xH2O; it is porous, so rusting continues. Source: Chemistry 11 KPK (taleem360.com), p. 388.
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Question 12
Galvanizing protects iron by coating it with:Show answer and explanation
Answer: D) Zinc
Coating with tin is called tinning. Source: Chemistry 11 KPK (taleem360.com), p. 388.
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Question 13
In electroplating, the article to be plated is made the:Show answer and explanation
Answer: A) Cathode
Metal ions are reduced and deposited on the cathode; the pure metal is the anode. Source: Chemistry 11 KPK (taleem360.com), p. 391.
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